SPECTRUM CHEMICAL MFG CORP. -- FORMALDEHYDE,37 % -- 6810-00-242-3643
===================== Product Identification ===================== Product ID:FORMALDEHYDE,37 % MSDS Date:12/17/1996 FSC:6810 NIIN:00-242-3643 === Responsible Party === Company Name:SPECTRUM CHEMICAL MFG CORP. Address:14422 SOUTH SAN PEDRO STREET City:GARDENA State:CA ZIP:90248-2027 Country:US Info Phone Num:310-516-8000 Emergency Phone Num:310-516-8000/800-424-9300(CHEMTREC) Preparer's Name:E. BRULL CAGE:63415 === Contractor Identification === Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 37% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2; 9596 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 200 PPM ACGIH TLV:S,200PPM/250STEL; 96 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 48% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 800 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, RESPIRATORY & GI TRACTS. ACUTE- SEVERE EYE IRRITATION, INJURY. MAY BE ABSORBED THROUGH SKIN. MAY CAUSE SKIN SENSITIZATION. INHALATION MAY CAUSE ALLERGIC SENSITIZATION, SE VERE RESPIRATORY IRRITATION. MAY BE FATAL IF INGESTED. MAY CAUSE BLINDNESS. CHRONIC- TOXIC TO NERVOUS SYSTEM. Explanation of Carcinogenicity:CONTAINS F [50-00-0] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:HEADACHE, BURNING OF NOSE & THROAT, SEVERE IRRITATION, SENSITIZATION, DERMATITIS, PAIN, BLURRED VISION, BLINDNESS, DEFATTING OF SKIN Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED CNS OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF CONSCIOUS, DRINK 2-4 CUPFULS OF MILK/WATER. SEEK IMMEDIATE MEDICAL ATTENTION. IF SPONTANEOUS VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF VOMITUS INTO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:140F,60C Autoignition Temp:Autoignition Temp Text:806F Lower Limits:6% METHANOL Upper Limits:36.5% MEOH Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY, FOAM FOR SMALL FIRE. USE FOAM, WATER SPRAY OR FOG FOR LARGE FIRE. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE EQUIPMENT. VENTILATE AREA. ELIMINATE SOURCES OF IGNITION. DILUTE WITH WATER. TAKE UP WITH SAND OR OTHER INERT ABSORBENT MATERIAL. TRANSFER INTO PROPER CONTAINER FOR RECYCLI NG OR DISPOSAL. USE WATER TO DISPERSE VAPORS. Neutralizing Agent:WATER ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA AWAY FROM IGNITION SOURCES AND STRONG OXIDIZING AGENTS. DO NOT INGEST. Other Precautions:TOXIC AND CORROSIVE. DO NOT GET IN EYES, ON SKIN/ON CLOTHING. AVOID INHALATION OF VAPORS. KEEP OUT OF REACH OF CHILDREN. OBEY HAZARD WARNING LABEL. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD/HOUSEHOL D USE. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. SELECT NIOSH-APPROVED RESPIRATOR BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE. IN EMERGENCY USE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:BUTYL OR NITRILE RUBBER. Eye Protection:SPLASH PROOF SAFETY GOGGLES/FACESHIELD. Other Protective Equipment:PROTECTIVE CLOTHING AND EQUIPMENT TO PREVENT ANY POSSIBILITY OF SKIN CONTACT. EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR DRINKING. Supplemental Safety and Health DIFFERENT FLASH POINT AND UN ID NUMBER. PNI B AND HCC PER TECHNICAL SUPPORT. ================== Physical/Chemical Properties ================== HCC:F7 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:197F,92C Vapor Pres:1950 @ 68F Vapor Density:1.04 Spec Gravity:0.89 pH:7 1% Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:LIQUID - STRONG ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATION IS RECOMMENDED. DO NOT CONTAMINATE ENVIRONMENT. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.